Based on the coexistence theory of metallic melts involving compound formation, the computational equations of mixing thermodynamic parameters were established by giving up some empirical parameters in the associated solution model. 以金属熔体共存理论为基础,通过舍弃缔合溶液模型中某些经验参数系统地制定了金属熔体混合热力学参数计算公式。
Based on the concept of local composition and two-liquid theory, a semi-empirical physical local composition model was proposed to correlate~ 1H NMR chemical shift of associated solution. The model contained two parameters denoting the intermolecular interaction energy. 本文基于局部组成思想和双液理论,提出了一个半经验的缔合体系核磁共振化学位移关联模型,模型中含有两个代表分子间相互作用力的待定参数。
Furthermore, the stability function and ideal associated solution model are employed to discuss the effect of stability of liquid PbO-PbCl_2 on the formation of complex ionic species. 此外,基于液相安定函数及理想会合熔体模型,讨论了PbO-PbCl2系液相安定性对熔体中形成氯氧化物复杂离子的影响。